Cast Iron

Cast iron usually refers to grey cast iron, but identifies a large group of ferrous alloys, which solidify with a eutectic. The color of a fractured surface can be used to identify an alloy. more...

White cast iron is named after its white surface when fractured due to its carbide impurities which allow cracks to pass straight through. Grey cast iron is named after its grey fractured surface, which occurs because the graphitic flakes deflect a passing crack and initiate countless new cracks as the material breaks.

Iron (Fe) accounts for more than 95 %wt of the alloy material, while the main alloying elements are carbon (C) and silicon (Si). The amount of carbon in cast irons is 2.1-4 %wt. Cast irons contain appreciable amounts of silicon, normally 1-3 %wt, and consequently these alloys should be considered ternary Fe-C-Si alloys. Despite this, the principles of cast iron solidification are understood from the binary iron-carbon phase diagram, where the eutectic point lies at 1154 °C and 4.3 wt% carbon. Since cast iron has nearly this composition, its melting temperature of 1150 to 1200 °C is about 300 °C lower than the melting point of pure iron.

Cast iron tends to be brittle, except for malleable cast irons. With its low melting point, good fluidity, castability, excellent machinability and wear resistance, cast irons have become an engineering material with a wide range of applications, including pipes, machine and car parts.

Production

Cast iron is made by remelting pig iron, often along with substantial quantities of scrap iron and scrap steel, and taking various steps to remove undesirable contaminants such as phosphorus and sulfur. Depending on the application, carbon and silicon content are reduced to the desired levels, which may be anywhere from 2% to 3.5% and 1% to 3% respectively. Other elements are then added to the melt before the final form is produced by casting.

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